Nitrene transfer from a sterically confined copper nitrenoid dipyrrin complex
نویسندگان
چکیده
A dipyrrin-supported copper complex mediates C–H bond amination and aziridination of exogenous substrates using electron-deficient arylazides, proceeding through copper-nitrene adducts.
منابع مشابه
Isocyanate and carbodiimide synthesis by nitrene-group-transfer from a nickel(II) imido complex.
The imido complex (dtbpe)Ni(N(2,6-(CHMe2)2C6H3)) reacts with CO and CNCH2Ph with addition at the Ni-N bond to give (dtbpe)Ni(C,N:eta 2-C(O)N(2,6-(CHMe2)2C6H3)) and (dtbpe)Ni(C,N:eta 2-C(NCH2Ph)N(2,6-(CHMe2)2C6H3)); both complexes react further with CO to liberate the isocyanate and carbodiimide ligands with formation of (dtbpe)Ni(CO)2.
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2023
ISSN: ['2041-6520', '2041-6539']
DOI: https://doi.org/10.1039/d3sc03641c